1. OBJECTIVES OF THE COURSE
• Identify the industrial and domestic sources of waste
and their characteristics;
• Develop knowledge of waste treatment disposal and
remediation processes;
• Understand the concepts of risk assessment and
remediation standards;
• Describe and share practical knowledge and technology
of chemical ,physical and biological treatment of
hazardous waste.
2. OBJECTIVES OF THE COURSE
• Describe and be able to apply the current remediation
processes and technologies;
• Understand the criteria behind selection of treatment
technologies and site remediation; and
• Educate communities and stakeholders on best
practices in waste management.
3. Waste Types and Sources
Definition of Wastes
“substances or objects which are disposed of
or are intended to be disposed of or are
required to be disposed of by the provisions
of the law”
Disposal means
“any operation which may lead to resource
recovery, recycling, reclamation, direct re-use
or alternative uses.
4. Solid wastes: domestic, commercial, mining and industrial
wastes especially common as co-disposal of wastes
Examples: plastics, styrofoam containers, bottles,
cans, papers, scrap iron, and other trash
Liquid Wastes: wastes in liquid form
Examples: domestic washings, chemicals, oils, waste
water from ponds, manufacturing industries
and other sources
5. Classification of Wastes according to their Properties.
Bio-degradable
can be degraded (paper, wood, fruits and others)
Non-biodegradable
cannot be degraded (plastics, bottles, old machines,
cans, styrofoam containers and others)
6. Classification of Wastes according to their Effects on
Human Health and the Environment
Hazardous wastes
Substances unsafe to use commercially, industrially, agriculturally,
or economically.
Non-hazardous
Substances safe to use commercially, industrially, agriculturally, or
economically.
7. TYPES OF WASTES
residential industrialcommercial
agricultural
mining
construction
Municipal solid waste Hazardous waste
8. PROBLEMS CAUSED BY IMPROPER
DISPOSAL OF WASTE
Threat to public health
rodents, insects = vectors of diseases (transmit
pathogens, typhoid, plague
poisonous materials
flammable materials
Irreversible environmental damage in ecosystems
terrestrial and aquatic
air pollution (incineration)
water pollution (land burial)
Technical and environmental difficulties
+administrative, economic and social problems
9. PROBLEMS WITH LAND DISPOSAL OF WASTE
• too little space for disposal
• costs
• harm to the environment and public health
• landfills are unreliable in long run
10. Refuse (municipal solid waste)
All non-hazardous solid waste from a community
Requires collection and transport to a processing or disposal site
Ordinary refuse: garbage + rubbish
Garbage
Highly decomposable food waste
Vegetable + meat
Rubbish
Glass, rubber, tin cans
Slowly decomposable or combustible material – paper, textile, wood
Trash
Bulky waste material that requires special handling
Mattress, TV, refrigerator
Collected separately
11. COMPOSITION OF URBAN SOLID WASTE
paper
hard waste
plastics
metals
food waste
glass
wood
other
• 0,6 – 1,2 m3 waste / day / person
• 120 – 250 kg / m3 without compaction
• 40-50% is paper
12. Responsibility of the local municipality
refuse collection vehicles
enclosed, compacting type with a capacity of 15 m3
compaction: 50% reduction
Frequency of collection and the point of pickup
depends:
type of community
population density
land use in the collection area
combined collection of garbage and rubbish is cheaper
for recycling it is essential to separate
separated collection!!! (paper, metal, plastic, glass,
organics, chemicals, batteries)
13. WASTE TREATMENT AND RESOURCE
RECOVERY
1. Reduce the total volume and weight of
material that requires disposal
Help to conserve land resources
2. Change the form or characteristic of waste
Composting, neutralizing, shredding, incineration
3. Recover natural resources and energy in the
waste material
Recycling and reuse!!! (it takes 17 trees to make 1 ton of
paper)
15.
Predominant method of waste disposal in developing
countries
Illegal dumping problems
Groundwater contamination, air pollution, pest and
health hazards
15
Open Dumps
19. What is a solid waste
• Any material that we discard, that is not liquid
or gas, is solid waste
– Municipal Solid Waste (MSW):
• Solid waste from home or office
– Industrial Solid Waste:
• Solid waste produced from Mines, Agriculture or
Industry
22. Benefits of Recycling
The ultimate benefits from recycling are
• cleaner land, air, and water,
• overall better health, and
• a more sustainable economy.
24. Open Dump
• Unsanitary, draws pests and vermin, harmful
runoff and leachates, toxic gases
• Still accounts for half of solid waste
25. Sanitary Landfill
• Sanitary Landfill
– Layer of compacted trash covered with a layer of earth
once a day and a thicker layer when the site is full
– Require impermeable barriers to stop escape of leachates:
can cause problem by overflow
– Gases produced by decomposing garbage needs venting
26. Sanitary Landfill
Leachates
• is any liquid that in passing through matter,
extracts solutes, suspended solids or any other
component of the material through which it has
passed.
• In the narrow environmental context leachate is
therefore any liquid material that drains from
land or stockpiled material and contains
significantly elevated concentrations of
undesirable material derived from the material
that it has passed through
27.
28. Sanitary Landfill
• Avoid:
– Swampy area/ Flood plains /coastal areas
– Fractures or porous rocks
– High water table
• Prefer:
– Clay layers
– Heads of gullies
29. Monitoring of Sanitary Landfills
• Gases: Methane, Ammonia, Hydrogen sulphide
• Heavy Metals: Lead, Chromium in soil
• Soluble substances: chloride, nitrate, sulfate
• Surface Run-offs
• Vegetation: may pick up toxic substances
• Plant residue in soil
• Paper/plastics etc – blown by the wind
30.
31. Incineration
Solves space problem but:
– produces toxic gases like Cl, HCl, HCN, SO2
– High temp furnaces break down hazardous compounds but
are expensive ($75 - $2000/ton)
– Heat generated can be recovered: % of waste burnt
32. Ocean Dumping
• Out of sight, free of emission control norms
• Contributes to ocean pollution
• Can wash back on beaches, and can cause death of
marine mammals
• Preferred method: incineration in open sea
• Ocean Dumping Ban Act, 1988: bans dumping of
sewage sludge and industrial waste
• Dredge spoils still dumped in oceans, can cause
habitat destruction and export of fluvial pollutants
33. Ways of Reducing Solid Waste
• Incineration, compacting
• Hog feed: requires heat treatment
• Composting: requires separation of organics from glass
and metals
• Recycling and Reusing
34.
35. Recycling: facts and figures
• In 1999, recycling and composting activities prevented
about 64 million tons of material from ending up in
landfills and incinerators. Today, this country recycles 32
percent of its waste, a rate that has almost doubled during
the past 15 years.
• 50 percent of all paper, 34 percent of all plastic soft drink
bottles, 45 percent of all aluminum beer and soft drink
cans, 63 percent of all steel packaging, and 67 percent of
all major appliances are now recycled.
• Twenty years ago, only one curbside recycling program
existed in the United States, which collected several
materials at the curb. By 2005, almost 9,000 curbside
programs had sprouted up across the nation. As of 2005,
about 500 materials recovery facilities had been
established to process the collected materials.
36.
37. Waste Exchange
• One persons waste can be another persons
raw material
• Isopropyl alcohol = cleaning solvent
• Nitric Acid from Electronic Industry = high
grade fertilizer
• Spent acid of steel industry = control for H2S
38. LANDFILL DESIGN
• Modern landfills are designed to
minimise these problems:
– Location
– Landfill Liner
– Compaction of waste
– Daily Cover
– Landfill Cap
– Leachate Management System
– Landfill Gas management System
39.
40. LANDFILL LOCATION
• In order to obtain a permit a landfill operator
must first carry out a detailed investigation
and prove to the satisfaction of the planning
authority and the EA that the site:
– is located in a geologically stable area
– is not located on a major aquifer;
– Is not located in a vulnerable area;
– is designed to reduce the risk of damage to
the environment and human health;
– will be monitored regularly for the duration of
operations and aftercare period.
42. LANDFILL LINERS
• Landfill Liners are constructed on the base
and sides of a landfill site to prevent leachate
from leaking into the surrounding soils.
• Landfill Liners may be constructed from:
– Compacted Clay
– Bentonite Enhanced Sand
– Geomembrane
– Geotextile Protector
– Dense Asphaltic Concrete (DAC)
– Combination of the above
46. LANDFILL LINERS
Construction of Dense
Asphaltic Concrete Liner
This is a new method of
lining landfills.
The first landfill to be
constructed with this
type of lining system in
the UK is North of
London and was
completed this summer.
48. CONSTRUCTION QUALITY ASSURANCE
• All construction carried out on landfill sites
is supervised and recorded by an
independent consultant.
• Following construction, certification reports
are produced by the consultant and issued to
the Environment Agency for approval.
49. LANDFILL OPERATIONS
• Waste is placed in layers approximately 3 m
thick and compacted.
• At the end of each working day
approximately 0.3 m of clay or sand
material is placed on top of the waste to:
– minimise the infiltration of rainwater
– isolate the waste from birds and vermin
– reduce odours
50. LANDFILL OPERATIONS
• To prevent wastage and the formation of
layers of weakness within the waste mass
the daily cover is scraped off and re-used
each day.
• Leachate that collects at the base of the
waste mass is collected and re-circulated
into the waste. This:
– increases the rate of decomposition of the waste
and therefore, rate of settlement;
– decreases disposal costs.
51. LANDFILL CAP
• Landfill caps placed above the waste
after completion of infilling prevent the
infiltration of rainwater, minimising the
production of leachate.
• Landfill Caps are usually constructed
from:
– Recompacted clay
– Geomembrane
54. LEACHATE MANAGEMENT SYSTEM
• Leachate management systems are installed to:
– prevent the accumulation of leachate in the base
of the landfill
– collect, re-circulate and dispose of leachate during
operations and after closure
• They comprise of:
– leachate drainage blanket at base of landfill
– pipes along base and sidewalls of landfill
– wells to monitor and extract the leachate
55. LANDFILL GAS MANAGEMENT SYSTEM
• Landfill gas management systems are
installed to prevent the build up of gases
within the landfill and to prevent migration of
landfill gas through the underlying strata.
• There are 2 ways landfill gas can be
managed:
– passive
– active
56. LANDFILL GAS MANAGEMENT SYSTEM
• Passive management systems
comprise of wells with perforated tops to
allow the gas to vent into the
atmosphere
• Active management systems involve the
active extraction of the gas.
• The extracted gas can be used to
generate electricity.
58. MONITORING
• Monitoring is carried out before, during, and
after the placement of waste.
• Numerous monitoring wells are constructed
around a landfill site (both upstream and
downstream) to check for contamination.
• Chemical testing is carried out regularly on:
– Groundwater
– Leachate
– Landfill Gas
59. 37/64
4- Landfills
Public/private ownership and operation
In most developing countries landfills are
owned and operated by local governments.
Where expertise is available in the private
sector, municipal planners should explore the
option of privatizing landfill operations on a
contractual basis. This option should be
weighed carefully in bases of cost recovery
and the payment of fees.
60. 38/64
4- Landfills
Monitoring and control of leachate:
Leachate management is a key factor in
safe landfill design and operation. The
natural decomposition of MSW and rain
infiltration into the site causes potentially
toxic contaminants. The wetter the climate is
the greater potential risks of ground- and
surface water contamination. The geology of
a site can exacerbate or reduce amount of
leachate.
61. 39/64
4- Landfills
Continue Monitoring and control of leachate:
Household hazardous waste (e.g., paint
products, garden pesticides, automotive
products, batteries) and hazardous wastes
from commercial and industrial generators
can release organic chemical and heavy
metals contaminants in leachate.
62. 40/64
4- Landfills
Continue Monitoring and control of leachate:
Natural or synthetic materials are used to
line the bottom and sides of landfills to
protect ground and surface water. Two feet
or more of compacted clay, thin sheets of
plastic made from a variety of synthetic
materials and others used in lining landfills.
Natural and synthetic liners can crack, if
improperly installed, or can lose strength
over time.
63. 41/64
4- Landfills
Continue Monitoring and control of leachate:
More than one liner or a mix of natural
and synthetic liners, called a composite
liner, is a recommended alternative. To
minimize production of leachate, covering
material should be applied after each day of
MSW is spread.
65. 43/64
4- Landfills
Leachate collection and treatment:
Leachate collection systems are installed above the
liner and consist of a perforated piping system which
collects and carries the leachate to a storage tank.
Periodically, leachate removed from the storage tank
and treated or disposed of.
Most common leachate management methods are:
discharge to wastewater treatment plant, on-site
treatment and recirculation back into the landfill.
66. 44/64
4- Landfills
Leachate recirculation
over waste in landfills showed an increase
the quantity (by factor of 10) and quality of
methane gas for recovery as well as possibly
reduces the concentration of contaminants in
leachate and enhances the settling of the waste.
67. 45/64
4- Landfills
Leachate reinjection may be appropriate for
areas with low rainfall. This technology could
be more cost-effective than other treatment
systems.
68. 46/64
4- Landfills
Possible drawbacks of leachate recirculation
include clogging of leachate collection systems,
increasing release of leachate to the
environment and increasing odor problems.
69. 47/64
4- Landfills
At controlled dumps monitoring operations
may involve the scheduled withdrawal of
samples to test for indicator contaminants such
as bacteria, heavy metal ions, and toxic organic
acids.
70. 48/64
4- Landfills
Monitoring operations at sanitary landfills
may involve computerized statistical sampling
and automatic reporting of results at the
regulatory agency. Such systems are costly and
require skilled personnel.
71. 49/64
4- Landfills
Monitoring and control of landfill gas
Gas management is required at sanitary landfills. At
controlled dumps, it should be monitoring to
determine if dangerous amounts of gas are being
released. A low-cost design (passive collection
system) to handle landfill gas consists of covered
vertical perforated pipes, using natural pressure of
gas to collect and vent or flare it at surface. More
costly active collection systems utilize covered
network of pipes and pumping to trap it. Gas is
processed and used for process heat or electricity.
This collection system is risky and expensive.
72. 50/64
4- Landfills
Continue Monitoring and control of landfill gas
Gas management is required at sanitary landfills. At
controlled dumps, it should be monitoring to
determine if dangerous amounts of gas are being
released. A low-cost design (passive collection
system) to handle landfill gas consists of covered
vertical perforated pipes, using natural pressure of
gas to collect and vent or flare it at surface. More
costly active collection systems utilize covered
network of pipes and pumping to trap it. Gas is
processed and used for process heat or electricity.
This collection system is risky and expensive.
73. 57/64
4- Landfills
Access and tipping area
Fencing should be designed to restrict unauthorized
access to the landfill and to keep out animals. A
staffed gate should be the point of entry to the facility
for vehicles and any waste pickers. Gate should be
equipped with scales for the weighing of vehicles as
they enter and exit the facility. They provide critical
information for planning purposes and for
operational management of collection vehicles.
74. 59/64
4- Landfills
Pre-processing and waste picker policy
Landfill is the least efficient alternative for materials
recovery operations. Where composting is attractive
at the landfill and/or waste picking activity is
permitted, sorting of the waste should occur close to
the gate or tipping area rather than at the working
cell. Such activities reduce the volume of material to
be landfilled and extend the life of the facility.
Waste picking policy should be established during
the design phase of the facility
75. 60/64
4- Landfills
Operations and safety manuals
Manuals should be prepared during the
design phase of the landfill. This permits their
content to be specifically adapted to the
processes for which the facility is designed.
Clear operating procedures and well-trained
workers are vital to safe and effective landfill
operations.
76. 61/64
4- Landfills
Closure/post-closure plans
Essential closure and post-closure elements are:
• Plans for the sealing and application of
final cover (including vegetation)
• Plans for long-term leachate and gas
management system monitoring;
77. 62/64
4- Landfills
Continue Closure/post-closure plans
• Plans for long-term ground and surface water
monitoring;
• Financial assurance guarantees to the local or
state government; and
• Land use restrictions for the site
78. 63/64
4- Landfills
In the case of controlled dumps in most
developing countries, closure and post-closure
plans are not prepared. However, ongoing
monitoring and control of the facility after its
useful life is an unavoidable for periods that
may exceed 30 years after their closure.
79. 64/64
4- Landfills
Community relations
The designer should establish a program for
ongoing dialog with community. This should
be based on transparency in landfill operations
and procedures to addressing community
concerns. Some facilities offer give-backs to
their host community.
81. Liquid Waste
• Sewage
• Highly toxic Industrial Waste & Used Oil
– Dilute and Disperse
– Concentrate and Contain
– Secure Landfill
• Sealed drums to be put in impermeable holds with monitoring
wells to check for leakage: does not work
– Deep well Disposal
• Pumping in deep porous layer bounded by impermeable
formations, well below water table
• $1 million to drill, $15-20/ton afterwards
• Restricted by geological considerations, can trigger earthquakes
84. Wastewater Treatment
Pre-treatment
- Occurs in business or industry
prior to discharge
- Prevention of toxic chemicals or
excess nutrients being discharged
in wastewater
85. Wastewater Treatment
Water discharged from homes, businesses,
and industry enters sanitary sewers
Water from rainwater on streets enters
storm water sewers
Combined sewers carry both sanitary
wastes and storm water
86. Wastewater Treatment
Water moves toward the
wastewater plant primarily by
gravity flow
Lift stations pump water from low
lying areas over hills
92. Wastewater Treatment
Measurement and sampling at the inlet
structure
- a flow meter continuously records the
volume of water entering the treatment
plant
- water samples are taken for determination
of suspended solids and B.O.D.
93. Wastewater Treatment
Suspended Solids – the quantity of solid
materials floating in the water column
B.O.D. = Biochemical Oxygen Demand
- a measure of the amount of oxygen
required to aerobically decompose organic
matter in the water
94. Wastewater Treatment
Measurements of Suspended Solids and
B.O.D. indicate the effectiveness of
treatment processes
Both Suspended Solids and B.O.D.
decrease as water moves through the
wastewater treatment processes
95. Wastewater Treatment
Primary Treatment
-- a physical process
-- wastewater flow is slowed down and
suspended solids settle to the bottom by
gravity
-- the material that settles is called sludge
or biosolids
99. Sludge from the primary sedimentation
tanks is pumped to the sludge
thickener.
- more settling occurs to concentrate
the sludge prior to disposal
Wastewater Treatment
100. Wastewater Treatment
Primary treatment reduces the suspended solids
and the B.O.D. of the wastewater.
From the primary treatment tanks water is
pumped to the trickling filter for secondary
treatment.
Secondary treatment will further reduce the
suspended solids and B.O.D. of the wastewater.
102. Wastewater Treatment
Secondary Treatment
Secondary treatment is a biological process
Utilizes bacteria and algae to metabolize
organic matter in the wastewater
In Cape Girardeau secondary treatment
occurs on the trickling filter
103. Wastewater Treatment
Secondary Treatment
the trickling filter does not “filter” the
water
water runs over a plastic media and
organisms clinging to the media remove
organic matter from the water
104. Wastewater Treatment
From secondary treatment on the trickling filter
water flows to the final clarifiers for further
removal of sludge.
The final clarifiers are another set of primary
sedimentation tanks.
From the final clarifiers the water is discharged
back to the Mississippi River.
106. Wastewater Treatment
Disposal of Sludge or Biosolids
-- the sludge undergoes lime
stabilization (pH is raised by addition of
lime) to kill potential pathogens
-- the stabilized sludge is land applied by
injection into agricultural fields
107. Wastewater Treatment
Disposal of Sludge or Biosolids
-- in the past, the sludge was disposed by
landfill or incineration
-- landfill disposal discontinued to the threat
of leachate
-- incineration discontinued because of the
ineffectiveness and cost
109. Wastewater Treatment
The wastewater plant lab conducts a
number of measurements and tests
on the water.
suspended solids temperature
B.O.D. nitrogen
pH phosphorus
110. Wastewater Treatment
In addition to test performed at the
wastewater lab, an off-site contract
lab performs additional tests
heavy metals priority pollutants
W.E.T (Whole Effluent Toxicity) tests
112. TRP Chapter 2.1 112
General definition
A hazardous waste has the potential to
cause an unacceptable risk to:
– PUBLIC HEALTH
– THE ENVIRONMENT
113. TRP Chapter 2.1 113
Why definition is difficult
HAZARDOUS WASTE
PHYSICAL FORM
PHYSICAL PROPERTIESCHEMICAL PROPERTIES
COMPOSITION
The hazard associated with a waste depends on:
BIOLOGICAL PROPERTIES
114. TRP Chapter 2.1 114
Examples of hazardous waste
definitions: Basel Convention
45 categories of wastes that are presumed to be
hazardous.
PLUS …...
These categories of waste need to exhibit one or
more hazardous characteristics:
flammable, oxidising, poisonous, infectious,
corrosive, ecotoxic
115. TRP Chapter 2.1 115
Examples of hazardous waste
definitions: UNEP
Wastes other than radioactive wastes which,
by reason of their chemical activity or toxic,
explosive, corrosive or other characteristics cause
danger or are likely to cause danger to health or the
environment
116. TRP Chapter 2.1 116
Examples of hazardous waste
definitions
UNDER United Nations REGULATIONS:
1 The waste is listed in UNEP regulations
2 The waste is tested and meets one of the four
characteristics established by UNEP:
• Ignitable
• Corrosive
• Reactive
• Toxic
3 The waste is declared hazardous by the generator
117. TRP Chapter 2.1 117
The objective of definitions
Why define wastes?
To decide whether or not that waste
should be controlled - this is
important for the generator as well as
the regulator
Why create a list?
•Clear and simple
•No need for testing
118. TRP Chapter 2.1 118
Different methods of classification
Lists eg Basel Convention Annex I, Basel List A,
EU European Waste Catalogue, US EPA list
Origin eg processes, Basel Convention Annex II
Hazardous characteristics eg toxicity, reactivity,
Basel Convention Annex III
Chemical and physical properties eg inorganic,
organic, oily, sludges
• Need to match classification to objectives
• No method will suit all cases
119. TRP Chapter 2.1 119
Methods of waste classification:
by origin
•Waste streams eg Basel Convention
•Miscellaneous or ubiquitous wastes eg
• contaminated soils
• dusts
• redundant pesticides from agriculture
• hospital wastes
120. TRP Chapter 2.1 120
Example of waste classification
by origin: Basel
The Basel Convention’s List of
Hazardous Waste Categories (Y1-Y18)
identifies wastes from specific
processes
eg Y1 Clinical wastes
Y6 Wastes from the production and
use of organic solvents
Y18 Residues from industrial waste
disposal operations
121. TRP Chapter 2.1 121
Methods of waste classification:
by hazardous characteristics
Main characteristics:
•Toxic
•Corrosive
UN Committee on the Transport of Dangerous Goods
by Road or Rail (ADR) lists waste characteristics.
These have been adopted by Basel Convention -
Annex III gives 13 characteristics, based on ADR
rules, including:
•Explosive
•Flammable
•Toxic and eco-toxic
Represented as codes H1-H13
•Ignitable
•Reactive
122. TRP Chapter 2.1 122
Hazardous characteristics:
Toxicity
Toxic wastes are harmful or fatal when ingested,
inhaled or absorbed through the skin
Examples:
•Spent cyanide solutions
•Waste pesticides
123. TRP Chapter 2.1 123
Hazardous characteristics:
Corrosivity
Acids or alkalis that are capable of dissolving human
flesh and corroding metal such as storage tanks
and drums
Examples:
•acids from metals cleaning
processes eg ferric chloride
from printed circuit board
manufacture
•liquor from steel
manufacture
124. TRP Chapter 2.1 124
Hazardous characteristics:
Ignitability
Ignitable wastes:
• can create fires under certain conditions
• or are spontaneously combustible
Examples:
•Waste oils
•Used solvents
•Organic cleaning materials
•Paint wastes
125. TRP Chapter 2.1 125
Hazardous characteristics:
Reactivity
Reactive wastes are unstable under ‘normal conditions’
They can cause:
• explosions
• toxic fumes
• gases or vapours
Examples:
• Peroxide solutions
• Hypochlorite solutions or solids
126. TRP Chapter 2.1 126
Hazardous characteristics:
Eco-toxicity
Eco-toxic wastes are harmful or fatal to other
species or to the ecological integrity of their habitats
Examples:
• Heavy metals
• Detergents
• Oils
• Soluble salts
127. TRP Chapter 2.1 127
Methods of waste classification:
by chemical, biological and
physical properties
• Inorganic wastes eg acids, alkalis, heavy metals,
cyanides, wastewaters from electroplating
• Organic wastes eg pesticides, halogenated and
non-halogenated solvents, PCBs
• Oily wastes eg lubricating oils, hydraulic fluids,
contaminted fuel oils
• Sludges eg from metal working, painting,
wastewater treatment
128. TRP Chapter 2.1 128
•Hazardous waste from households - outside the controls in
many countries
•Small quantity generators - often placed outside the system, at
least initially
•Aqueous effluents discharged to sewer or treated on-site -
controlled separately from hazardous wastes in most countries
•Sewage sludge - excluded in some countries
•Mining wastes - often excluded
•Agricultural waste - often excluded
•Nuclear waste - always excluded
Exclusions from control systems
Some wastes may be excluded from the legal
definition of hazardous wastes, and thus not
subject to controls. These vary, but may include:
130. TRP Chapter 6.5 130
Definitions
Thermal treatment = destruction of hazardous waste by
thermal decomposition
Thermal treatment methods include:
• incineration - complete combustion using excess
oxygen
• gasification - incomplete combustion in the partial
absence of oxygen
• pyrolysis - thermal decomposition in the total
absence of oxygen
131. TRP Chapter 6.5 131
Application of thermal treatment
Suitable for organic wastes
Thermal treatment processes:
• require high capital investment
• are highly regulated
• need skilled personnel
• require high operating and safety
standards
• have medium to high operating costs
132. TRP Chapter 6.5 132
Good practice in hazardous waste
combustion
3 Ts:
•Time
•Temperature
•Turbulence
Flue gas cleaning systems
133. TRP Chapter 6.5 133
Waste characteristics
Different waste types have different heat values ie
the amount of heat released during complete
combustion - Calorific Value (CV)
• Gross Calorific Value (CV) includes heat released
by steam condensation
• Net Calorific Value does not include the heat from
condensation
Also important:
•Flash point
•Viscosity
•Chlorine, fluorine, sulphur & heavy metals
134. TRP Chapter 6.5 134
Examples of Calorific Value
Mixed waste from plant
cleaning operations 10,000 - 30,000 kj/kg
Wastewater 5,000 kj/kg
(0 - 10,000kj/kg depending on organic content)
Industrial sludge 1,000 - 10,000 kj/kg
Paints and varnishes >20,000 kj/kg
Chlorinated hydrocarbons 5,000 - 20,000 kj/kg
For comparison, MSW = ~10,000kj/kg
Source: Indaver
135. TRP Chapter 6.5 135
Combustion
Requires:
•addition of excess air
•mechanical mixing of waste
•even distribution and aeration of waste
Behaviour of waste during combustion varies
according to its heat value and its form
Some low CV wastes burn easily = straw
Some low CV wastes are difficult to burn = wet sludges
Some high CV wastes burn easily = tank bottoms
Some high CV wastes are difficult to burn = contaminated
soils, certain plastics
Certain wastes change their physical
characteristics during combustion
136. TRP Chapter 6.5 136
Combustion techniques
Bed plate furnaces: use gravity to mix waste - used for
homogeneous and wet wastes such as sludge cake
Fluidised bed furnaces: waste is introduced into a bed of
sand which is kept in suspension - used for wastes of
similar size and density
Incineration grates: wastes fed onto the grate are turned or
moved to ensure aeration of the waste mass via holes in the
grate - used for solid wastes eg municipal wastes, not
liquids or sludges
Rotary kilns: wastes are placed in slowly rotating furnace -
suitable for solids, sludges and liquids
137. TRP Chapter 6.5 137
Operation of the furnace
• good understanding of waste
characteristics
• technical skills
• control of waste feed
• mixing of wastes
• temperature to be kept at required
level despite variations in waste
• excess air
• flue gas control
• regular maintenance
Must be consistent
Needs:
Source: David C Wilson
138. TRP Chapter 6.5 138
Energy recovery
Waste combustion produces heat
but combustion of low CV wastes may not be self-supporting
Energy recovery is via production of steam to
generate electricity
• Only steam production: 80% efficiency is typical
• Steam can be used for in-house demands
• Steam can be delivered to adjacent users eg other industrial
plants
• Electricity can be generated: 25% efficiency typical
Opportunities to sell heat are improved where
facilities are in industrial areas
Sale of surplus energy improves plant economics
139. TRP Chapter 6.5 139
By-products of incineration
May be:
• solid
• liquid
• gaseous
Comprise:
• recovered materials such as metals, HCl
• flue gases
• slag and ash
• products of the flue gas treatment, also
called air pollution control (APC) residues
• wastewater
140. TRP Chapter 6.5 140
Solid residues
•bottom ash or slag
•fly ash
•air pollution control (APC) residues
Terms and regulations on treatment and
disposal of solid residues differ between
countries
Bottom ash may be landfilled or used as an
aggregate substitute eg for road building
141. TRP Chapter 6.5 141
Flue gases
Quantity and type of pollutants
in emissions depend on:
•pollutants in waste
• technology
•efficiency of operation
Average 6 - 7 Nm3 of flue gas
per kg waste
Specific collection/treatment for:
Dust - staged filters
Chlorine - neutralised by scrubbing with lime
Sulphur - washing stage
Dioxins - combustion control, activated carbon
Source: David C Wilson
142. TRP Chapter 6.5 142
Dioxins
• Family of around 200 chlorinated organic
compounds, a few of which are highly toxic
• Widespread in the environment
• Present in waste going to incineration
• Can be re-formed in cooling stages post-combustion
• 3Ts help destroy dioxins in waste, reduce reformation
• Use of activated carbon to filter from flue gases
• Emissions limits extremely low
143. TRP Chapter 6.5 143
Example of flue gas cleaning
technology
Source: Indaver
144. TRP Chapter 6.5 144
Wastewater from incineration
•Controls vary from country to country
•Quantity:
• influenced by gas scrubbing technology
chosen ie wet, semi-dry, dry
•Treatment:
• in aerated lagoons
• widely used
• low cost
• may not meet required standard
• physico-chemical treatment may also be
needed
145. TRP Chapter 6.5 145
Measurement
Of what:
•controlled parameters eg carbon monoxide
How:
•regular
•continuous
Set out in:
•national regulations
•permitted operating conditions
Problems:
·Measuring equipment may be imprecise
·Errors in correlation
·Errors in sampling
146. TRP Chapter 6.5 146
Measurement: an example
Emissions from rotary kiln incinerator
Continuous monitoring for:
HCl, CO, dust, SO2, HF, TOC, Nox, O2
Monthly measurement for:
9 heavy metals
Twice a year (soon to be continuous):
PCDD/PCDF
ALSO monitored: wastewater and solid residues
Source: Indaver, Belgium
147. TRP Chapter 6.5 147
Costs
• Related to site-specific and country-specific factors
• High level of sophistication & control = high
construction costs
• Air pollution control costs = 30-40% of total
• Treatment costs per tonne similar to other
technologies
• Cost savings because volume, weight and hazard of
waste remaining for disposal greatly reduced
• Recovery and sale of energy/heat from the process
improves economics
148. TRP Chapter 6.5 148
Cement kiln incineration
Widely used for range of hazardous wastes eg oily
wastes, wastewaters, sludges, solvents, organic
compounds
Provides:
•good combustion conditions
•alkaline environment
•vacuum operation
•high thermal inertia
•no impact on quality of cement product
•opportunity to recover energy content of waste
•no by products
149. TRP Chapter 6.5 149
Requirements for co-combustion
in cement kilns
• suitable for pumpable organic wastes
• not suitable for wastes with high water,
sulphur, chlorine, heavy metals content
• waste needs pre-treatment/blending for use
as fuel
• adaptations may be needed eg fuel feed,
dust controls
• must meet Health and Safety concerns re
handling of hazardous wastes
• dependent on demand for product
150. TRP Chapter 6.5 150
Examples of technology 1
Rotary kiln incinerator
Source: Guyer, Howard H Industrial processes and waste stream management, Wiley
151. TRP Chapter 6.5 151
Examples of technology 2
Fluidised bed combustion
Circulating fluidised bed Bubbling fluidised bed
Source: Guyer, Howard H Industrial processes and waste stream management, Wiley
152. TRP Chapter 6.5 152
Pyrolysis
Pyrolysis = thermal decomposition process which
takes place in the total absence of oxygen
Products of pyrolysis:
•combustible gases
•mixed liquid residue
Advantages:
•low operating temperature
•no need for excess air so less flue gas
•by-products are combustible
153. TRP Chapter 6.5 153
Application of pyrolysis
For single waste streams
such as:
•scrap tyres
•waste plastics
For treatment of
contaminated soils
154. TRP Chapter 6.5 154
Gasification
Gasification = incomplete combustion in the
partial absence of oxygen
Enables efficient destruction of hazardous waste
at lower temperatures than incineration
Thermal destruction is ensured by a combination
of high-temperature oxidation followed by high
temperature reduction
Products:
•useful gases eg hydrogen, carbon monoxide
•solid char
155. TRP Chapter 6.5 155
Key considerations
• Waste reduction and avoidance by generators
should always be a priority
• Need to consider residues from treatment
processes and their disposal
• Thermal treatment is the best available
technology for some organic hazardous wastes
- providing that it is designed, managed and
operated properly
• There is often opposition from the public and
from environmental groups, largely based on
dioxin concerns
156. TRP Chapter 6.5 156
Summary
Thermal treatment:
• is suitable for organic wastes
• includes different technologies, all require high
capital investment
• is highly regulated, requires high operating and
safety standards
• needs skilled personnel
• has medium to high operating costs
• generates useful energy
• has by-products which need careful handling
• often attracts opposition
164. TRP Chapter 4.2 164
Waste minimisation opportunities
applicable to all operations 1
•Use higher purity materials
•Use less toxic raw materials
•Use non-corrosive materials
•Convert from batch to continuous process
•Improve equipment inspection & maintenance
•Improve operator training
•Improve supervision
•Improve housekeeping
165. Waste minimisation opportunities
applicable to all operations 2
Improve material tracking and inventory
control:
•avoid over-purchasing
•inspect deliveries before acceptance
•make frequent inventory checks
•label all containers accurately
•ensure materials with limited shelf-life are
used by expiry date
•where possible, install computer-assisted
inventory control
167. TRP Chapter 4.2 167
Implementing a company waste
minimisation programme
• A systematic and ongoing effort to reduce
waste generation
• Must be tailored to specific company
needs and practices
• 3 main phases:
• planning and organisation
• conducting a waste audit
• implementing, monitoring and reviewing
168. TRP Chapter 4.2 168
Phase 1: Planning and
organisation
•Obtain management commitment
•Establish programme task force
•Set goals and priorities
•Establish an audit team
169. TRP Chapter 4.2 169
Phase 2: Waste audit
6 main steps:
identify plant operations
define process inputs
define process outputs
assess material balance
identify opportunities
conduct feasibility study
170. TRP Chapter 4.2 170
Step 1: Identify plant operations
• Inspect the site
• Identify different processes undertaken on site
• List processes and obtain as much
information as possible on them
171. TRP Chapter 4.2 171
Step 2: Define process inputs
Account for all the material flows into each
individual process
•materials
•energy
•water
Make sure all inputs are accounted for in
detail eg kg of raw materials, kilowatts of
electricity, litres of water
Make sure figures are on same basis
eg annual, monthly, weekly inputs
172. TRP Chapter 4.2 172
Step 3: Define process outputs
Identify and quantify all process outputs
•primary products
•co-products
•waste for re-use or recycling
•waste for disposal
173. TRP Chapter 4.2 173
Step 4: Assess material balance
To ensure that all resources are accounted
for, conduct a materials balance assessment
=Total
material in
Total
material
out
+ Product
174. TRP Chapter 4.2 174
Typical components of a material
balance
Inputs Outputs
Production
process or unit
operation
Raw material 1
Raw material 2
Raw material 3
Water/air
Product
By-product
Wastewater
Wastes for storage or
off-site disposal
Gaseous emissions
175. TRP Chapter 4.2 175
Step 5: Identify opportunities for
waste minimisation
Using data acquired during the waste
audit, make preliminary evaluation of the
potential for waste minimisation
Prioritise options for implementation
176. TRP Chapter 4.2 176
Step 6: Conduct feasibility study
Conduct feasibility analysis of selected options
Technical considerations:
•Availability of technology
•Facility constraints including compatibility
with existing operation
•Product requirements
•Operator safety and training
•Potential for health and environmental
impacts
Economic considerations:
•Capital and operating costs
•Pay-back period
177. TRP Chapter 4.2 177
Phase 3: Implementing,
monitoring and reviewing
•Prepare Action Plan
•Identify resources
•Implement the measures
•Evaluate performance
178. TRP Chapter 4.2 178
Summary
•There are a number of good reasons for minimising
waste - source reduction comes at the top of the
waste hierarchy
•Factors which influence waste minimisation include
regulations, technological feasibility, economic
viability and management support
•There are both incentives and barriers; some
opportunities widely applicable - and valuable
experience from demonstration projects
•Guide to implementing a company waste
minimisation programme and conducting an audit