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The Chemistry of Life
Chapter 2
Chemistry
   All living things depend on chemistry
    ◦ The structure and function of all living
      things are governed by the laws of
      chemistry
 Why is it important to understand
  chemistry in biology?
 Biologists study chemistry because all
  living things are made of the same
  kinds of matter that make up nonliving
  things
Section 1

COMPOSITION OF
MATTER
Matter
 Everything in the universe is made of
  matter
 Matter is anything that occupies
  space and has mass
 Mass is the quantity of matter an
  object has
Elements and Atoms
 Elements are substances that cannot
  be broken down chemically into
  simpler kinds of matter
 Information about elements is
  summarized on a chart called the
  periodic table
 The simplest particle of an element
  that retains all of the properties of that
  element is an atom
Elements and Atoms
The nucleus
   Nucleus – the central region that
    makes up the bulk of the mass of the
    atom
    ◦ Consists of:
      Protons – positively charged particles
      Neutrons – particles with no charge
Electrons
 Net electrical charge of an atom is
  zero
 Electrons – small, negatively charged
  particles
    ◦ Move around the nucleus at very high
      speeds
    ◦ Located in orbitals – regions around a
      nucleus that show the probable location of
      an electron
      Orbitals correspond to specific energy levels
Elements
 Atomic Number = number of protons
  in an element
 Mass Number = total number of
  protons and neutrons in the atom
Isotopes
   Atoms of the same element that have
    a different number of neutrons

   Average atomic mass of an element
    takes into account the relative
    amounts of each isotope in the
    element
PRACTICE
   In groups, we are going to practice
    drawing elements on white boards

   Group 1 – Draw and identify the
    element that has 6 protons, 6
    neutrons, and 6 electrons

   Group 2 – Draw and identify the
    element that has 7 protons, neutrons,
    and electrons
PRACTICE
   Group 3 – 8 protons, neutrons, and electrons
   Group 4 – 15 protons, 16 neutrons, and 15
    electrons
   Group 5 – 16 protons, neutrons, and electrons
   Group 6 – 11 protons, 12 neutrons, and 11
    electrons
   Group 7 – 13 protons, 14 neutrons, and 13
    electrons
   Group 8 – 19 protons, 20 neutrons, and 19
    electrons
   Group 9 – 26 protons, 29 neutrons, and 26
    electrons
Compounds
   Compounds are made up of atoms of
    two or more elements in fixed
    proportions
    ◦ Chemical formula shows the kinds and
      proportions of atoms of each element that
      forms a particular compound (Ex: H20)
   Compounds usually very different from
    the elements that form them
    ◦ Sodium – soft metal
    ◦ Chlorine – poisonous gas
    ◦ Sodium chloride – table salt
Compounds
   Most atoms are not stable in their
    natural state, so they tend to react
    with other atoms in different ways to
    become more stable

   Chemical bonds are the attractive
    forces that hold atoms together
Ionic Bonds                     Covalent Bonds

   Formed when one or             Formed when electrons
    more electrons are              are shared between
    transferred from one            atoms
    atom to another                 ◦ Single, double, and triple
                                      bonds

   Ion – atom or molecule
    with an electrical charge      Molecule – simplest part
    (Na+, Cl-)                      of a substance that
                                    retains all of the
                                    properties of that
                                    substance and can exist
                                    in a free state
              Chemical Bonds
Section 2

ENERGY
Energy
 All living things use energy
 Amount of energy in the universe
  stays the same
 Can change from one form to another
 Transfer of energy is very important in
  biology
Energy and Matter
   Energy – the ability to do work
    ◦ Occurs in various forms and one form of
      energy can be changed to another form
   Important forms of energy in biological
    systems
    ◦ Chemical, thermal, electrical, and
      mechanical
States of Matter
 The atoms and molecules in any
  substance are in constant motion
 The motion and spacing between
  atoms or molecules determine the
  substances state: solid, liquid, or gas
States of Matter
States of Matter
   http://www.harcourtschool.com/activity
    /states_of_matter/
Energy and Chemical
Reactions
   Chemical Reaction – one or more
    substances change to produce one or
    more different substances
    ◦ Energy is absorbed or released when
      chemical bonds are broken and new ones
      are formed
    ◦ Living things undergo many thousands of
      chemical reactions every day
Energy and Chemical
Reactions
               Reactants –
                substances or
                molecules that
                participate in a
                chemical reaction
               Products –
                substances that
                form in a chemical
                reaction
Energy and Chemical
Reactions
   Metabolism – the sum of all the
    chemical reactions that occur in an
    organism
    ◦ Energy your body needs is provided by
      sugars, proteins, and fats found in foods
    ◦ Body continuously undergoes chemical
      reactions to break down stored energy
      from foods into substances your body can
      use for energy
Activation Energy
 Activation Energy – the amount of
  energy needed to start a chemical
  reaction
 Catalysts – chemical substances that
  reduce the amount of activation
  energy that is needed for a reaction to
  take place
    ◦ Enzymes – biological molecule that
      speeds up metabolic reactions without
      being permanently changed or destroyed
Activation Energy
Section 3

WATER AND SOLUTIONS
Water and Solutions
 Chemical reactions of all living things
  take place in the watery environment
  of the cell
 Water has several unique properties
  that make it one of the most important
  compounds found in living things
Polarity
   Polar – compounds with an uneven
    distribution of positive and negative
    charges
Solubility of Water
   The polar nature of water allows it to
    dissolve polar substances, such as
    sugars, ionic compounds, and some
    proteins

   Water does not dissolve nonpolar
    substances such as fats like oil
Solubility of Water
Hydrogen Bonding
                The polar nature of
                 water causes water
                 molecules to be
                 attracted to one
                 another
                Hydrogen bond –
                 the force of
                 attraction between a
                 hydrogen molecule
                 with a partial positive
                 charge and another
                 atom or molecule
                 with a partial or full
                 negative charge
Cohesion                       Adhesion

   An attractive force that      An attractive force
    holds molecules of a           between two particles of
    single substance               different substances
    together




      Cohesion and Adhesion
Capillary Action

   Attraction between
    molecules that results in
    the rise of the surface of
    a liquid when in contact
    with a solid




      Cohesion and Adhesion
Questions
 How are cohesion and adhesion
  similar?
 How are they different?
 How do they contribute to capillarity?
Density of Ice
   Solid water is less
    dense than liquid
    water
    ◦ This is opposite of
      all other substances
   Hydrogen bonding
    causes ice crystals
    to have large
    amounts of open
    space
Why is it important that ice is
less dense than water?
 When bodies of water freeze, they
  freeze from the top down
 Ice insulates the water below from the
  cold air, which allows fish and other
  aquatic animals to survive under the
  icy surface
Solutions
   Solution – a mixture in which one or
    more substances are uniformly
    distributed in another substance
    ◦ Solute – substance dissolved in the
      solvent (may be ions, atoms, or
      molecules)
    ◦ Solvent – substance in which the solute
      is dissolved
   Sugar dissolved in water – which one
    is the solvent and which is the solute?
Solutions
 Solutions can be composed of various
  proportions of a given solute in a given
  solvent
 Concentration of a solution is the
  amount of solute dissolved in a fixed
  amount of the solution
 A saturated solution is one in which
  no more solute can dissolve
Solubility of Water
Solutions
   Aqueous solutions – solutions in
    which water is the solvent
    ◦ Important to living things
      Marine microorganisms spend their lives in the
       sea
      Most nutrients plants need are in aqueous
       solutions in moist soil
      Body cells exist in an aqueous solution and are
       filled with aqueous solution
Important Properties of Water
Property   What It Does/Means        Importance
Cohesion Water molecules stick       Movement of water in plants,
         together                    surface tension
Adhesion   Water sticks to another   capillarity
           substance
High heat Absorb and release large Stabilizes global temps, keep
capacity  amounts of heat energy   cells at even temps
          without a big change in
          temp
Solvent    Water can dissolve many   Marine organisms, plant
           different substances      nutrients, body cells
Acids and Bases
   What do the words acid and base
    mean?
Ionization of Water
 As water molecules move, they bump
  into each other
 Some of these collisions are strong
  enough to result in a chemical change
 One water molecule loses a proton
  while another gains a proton
Ionization of Water
Ionization of Water
 H3O+ : Hydronium Ion
 OH- : Hydroxide Ion


   Acidity or alkalinity is a measure of the
    relative amounts of hydronium ions
    and hydroxide ions dissolved in a
    solution
Acids                           Bases

   Number of hydronium            Number of hydronium
    ions (H3O+ ) GREATER            ions (H3O+ ) LESS than
    than the number of              the number of hydroxide
    hydroxide ions (OH-)            ions (OH-)
   Tend to have a sour taste      Alkaline
                                   Bitter taste




             Acids and Bases
pH
      pH scale – scale
       for comparing the
       relative
       concentrations of
       hydronium ions
       and hydroxide ions
       in a solution
      Ranges from 0 to
       14
      Change in 1 pH
       unit is a 10-fold
       change in acidity or
       alkalinity
Buffers
   Buffers are chemical substances that
    neutralize small amounts of either an
    acid or a base added to a solution

 Control of pH is important for living
  systems
 Enzymes can function only within a
  very narrow pH range

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Chapter 2 - Basic Chemistry

  • 1. The Chemistry of Life Chapter 2
  • 2. Chemistry  All living things depend on chemistry ◦ The structure and function of all living things are governed by the laws of chemistry  Why is it important to understand chemistry in biology?  Biologists study chemistry because all living things are made of the same kinds of matter that make up nonliving things
  • 4. Matter  Everything in the universe is made of matter  Matter is anything that occupies space and has mass  Mass is the quantity of matter an object has
  • 5. Elements and Atoms  Elements are substances that cannot be broken down chemically into simpler kinds of matter  Information about elements is summarized on a chart called the periodic table  The simplest particle of an element that retains all of the properties of that element is an atom
  • 7. The nucleus  Nucleus – the central region that makes up the bulk of the mass of the atom ◦ Consists of:  Protons – positively charged particles  Neutrons – particles with no charge
  • 8. Electrons  Net electrical charge of an atom is zero  Electrons – small, negatively charged particles ◦ Move around the nucleus at very high speeds ◦ Located in orbitals – regions around a nucleus that show the probable location of an electron  Orbitals correspond to specific energy levels
  • 9. Elements  Atomic Number = number of protons in an element  Mass Number = total number of protons and neutrons in the atom
  • 10. Isotopes  Atoms of the same element that have a different number of neutrons  Average atomic mass of an element takes into account the relative amounts of each isotope in the element
  • 11. PRACTICE  In groups, we are going to practice drawing elements on white boards  Group 1 – Draw and identify the element that has 6 protons, 6 neutrons, and 6 electrons  Group 2 – Draw and identify the element that has 7 protons, neutrons, and electrons
  • 12. PRACTICE  Group 3 – 8 protons, neutrons, and electrons  Group 4 – 15 protons, 16 neutrons, and 15 electrons  Group 5 – 16 protons, neutrons, and electrons  Group 6 – 11 protons, 12 neutrons, and 11 electrons  Group 7 – 13 protons, 14 neutrons, and 13 electrons  Group 8 – 19 protons, 20 neutrons, and 19 electrons  Group 9 – 26 protons, 29 neutrons, and 26 electrons
  • 13. Compounds  Compounds are made up of atoms of two or more elements in fixed proportions ◦ Chemical formula shows the kinds and proportions of atoms of each element that forms a particular compound (Ex: H20)  Compounds usually very different from the elements that form them ◦ Sodium – soft metal ◦ Chlorine – poisonous gas ◦ Sodium chloride – table salt
  • 14. Compounds  Most atoms are not stable in their natural state, so they tend to react with other atoms in different ways to become more stable  Chemical bonds are the attractive forces that hold atoms together
  • 15. Ionic Bonds Covalent Bonds  Formed when one or  Formed when electrons more electrons are are shared between transferred from one atoms atom to another ◦ Single, double, and triple bonds  Ion – atom or molecule with an electrical charge  Molecule – simplest part (Na+, Cl-) of a substance that retains all of the properties of that substance and can exist in a free state Chemical Bonds
  • 17. Energy  All living things use energy  Amount of energy in the universe stays the same  Can change from one form to another  Transfer of energy is very important in biology
  • 18. Energy and Matter  Energy – the ability to do work ◦ Occurs in various forms and one form of energy can be changed to another form  Important forms of energy in biological systems ◦ Chemical, thermal, electrical, and mechanical
  • 19. States of Matter  The atoms and molecules in any substance are in constant motion  The motion and spacing between atoms or molecules determine the substances state: solid, liquid, or gas
  • 21. States of Matter  http://www.harcourtschool.com/activity /states_of_matter/
  • 22. Energy and Chemical Reactions  Chemical Reaction – one or more substances change to produce one or more different substances ◦ Energy is absorbed or released when chemical bonds are broken and new ones are formed ◦ Living things undergo many thousands of chemical reactions every day
  • 23. Energy and Chemical Reactions  Reactants – substances or molecules that participate in a chemical reaction  Products – substances that form in a chemical reaction
  • 24. Energy and Chemical Reactions  Metabolism – the sum of all the chemical reactions that occur in an organism ◦ Energy your body needs is provided by sugars, proteins, and fats found in foods ◦ Body continuously undergoes chemical reactions to break down stored energy from foods into substances your body can use for energy
  • 25. Activation Energy  Activation Energy – the amount of energy needed to start a chemical reaction  Catalysts – chemical substances that reduce the amount of activation energy that is needed for a reaction to take place ◦ Enzymes – biological molecule that speeds up metabolic reactions without being permanently changed or destroyed
  • 27. Section 3 WATER AND SOLUTIONS
  • 28. Water and Solutions  Chemical reactions of all living things take place in the watery environment of the cell  Water has several unique properties that make it one of the most important compounds found in living things
  • 29. Polarity  Polar – compounds with an uneven distribution of positive and negative charges
  • 30. Solubility of Water  The polar nature of water allows it to dissolve polar substances, such as sugars, ionic compounds, and some proteins  Water does not dissolve nonpolar substances such as fats like oil
  • 32. Hydrogen Bonding  The polar nature of water causes water molecules to be attracted to one another  Hydrogen bond – the force of attraction between a hydrogen molecule with a partial positive charge and another atom or molecule with a partial or full negative charge
  • 33. Cohesion Adhesion  An attractive force that  An attractive force holds molecules of a between two particles of single substance different substances together Cohesion and Adhesion
  • 34. Capillary Action  Attraction between molecules that results in the rise of the surface of a liquid when in contact with a solid Cohesion and Adhesion
  • 35. Questions  How are cohesion and adhesion similar?  How are they different?  How do they contribute to capillarity?
  • 36. Density of Ice  Solid water is less dense than liquid water ◦ This is opposite of all other substances  Hydrogen bonding causes ice crystals to have large amounts of open space
  • 37. Why is it important that ice is less dense than water?  When bodies of water freeze, they freeze from the top down  Ice insulates the water below from the cold air, which allows fish and other aquatic animals to survive under the icy surface
  • 38. Solutions  Solution – a mixture in which one or more substances are uniformly distributed in another substance ◦ Solute – substance dissolved in the solvent (may be ions, atoms, or molecules) ◦ Solvent – substance in which the solute is dissolved  Sugar dissolved in water – which one is the solvent and which is the solute?
  • 39. Solutions  Solutions can be composed of various proportions of a given solute in a given solvent  Concentration of a solution is the amount of solute dissolved in a fixed amount of the solution  A saturated solution is one in which no more solute can dissolve
  • 41. Solutions  Aqueous solutions – solutions in which water is the solvent ◦ Important to living things  Marine microorganisms spend their lives in the sea  Most nutrients plants need are in aqueous solutions in moist soil  Body cells exist in an aqueous solution and are filled with aqueous solution
  • 42. Important Properties of Water Property What It Does/Means Importance Cohesion Water molecules stick Movement of water in plants, together surface tension Adhesion Water sticks to another capillarity substance High heat Absorb and release large Stabilizes global temps, keep capacity amounts of heat energy cells at even temps without a big change in temp Solvent Water can dissolve many Marine organisms, plant different substances nutrients, body cells
  • 43. Acids and Bases  What do the words acid and base mean?
  • 44. Ionization of Water  As water molecules move, they bump into each other  Some of these collisions are strong enough to result in a chemical change  One water molecule loses a proton while another gains a proton
  • 46. Ionization of Water  H3O+ : Hydronium Ion  OH- : Hydroxide Ion  Acidity or alkalinity is a measure of the relative amounts of hydronium ions and hydroxide ions dissolved in a solution
  • 47. Acids Bases  Number of hydronium  Number of hydronium ions (H3O+ ) GREATER ions (H3O+ ) LESS than than the number of the number of hydroxide hydroxide ions (OH-) ions (OH-)  Tend to have a sour taste  Alkaline  Bitter taste Acids and Bases
  • 48. pH  pH scale – scale for comparing the relative concentrations of hydronium ions and hydroxide ions in a solution  Ranges from 0 to 14  Change in 1 pH unit is a 10-fold change in acidity or alkalinity
  • 49. Buffers  Buffers are chemical substances that neutralize small amounts of either an acid or a base added to a solution  Control of pH is important for living systems  Enzymes can function only within a very narrow pH range